Oxidation of Vicinal Diketones with Manganese(III) Fluoride

Oxidation of Vicinal Diketones with Manganese(III) Fluoride

Vicinal diketones were oxidised, at room temperature, to carboxylic acids by manganese(III) fluoride with 90% yield. Investigation of the kinetics suggested that the reaction proceeded via a cyclic intermediate.

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Veröffentlicht in:Journal of chemical research 2003-10, Vol.2003 (10), p.635-637
Hauptverfasser: Duvaux, Dorothee, Ho, Jason, Hughes, DEPeter
Format: Artikel
Sprache:eng
Schlagworte:
Carboxylic acids
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Zusammenfassung:Vicinal diketones were oxidised, at room temperature, to carboxylic acids by manganese(III) fluoride with 90% yield. Investigation of the kinetics suggested that the reaction proceeded via a cyclic intermediate.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823403322656229