C-H functionalization of tetramethylsilane employing a borylnitrene

C-H functionalization of tetramethylsilane employing a borylnitrene

The irradiation of 2-azido-4,4,5,5-tetramethyl-1,3,2-dioxaborol (pinBN3, pin = pinacolato) generates the corresponding borylnitrene that easily inserts into the CH bond of tetramethylsilane. This primary photoproduct, a monoborylated aminoborane, undergoes a subsequent reaction with pinBN3 forming a...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (100), p.11773-11775
Hauptverfasser: Müller, Matthias, Maichle-Mössmer, Cäcilia, Bettinger, Holger F
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
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Beschreibung
Zusammenfassung:The irradiation of 2-azido-4,4,5,5-tetramethyl-1,3,2-dioxaborol (pinBN3, pin = pinacolato) generates the corresponding borylnitrene that easily inserts into the CH bond of tetramethylsilane. This primary photoproduct, a monoborylated aminoborane, undergoes a subsequent reaction with pinBN3 forming a bisborylated aminoborane.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47753c