Direct Trifluoromethylation of the CH Bond

Trifluoromethylation meets CH activation: after transition metal‐catalyzed trifluoromethylation became more and more popular, trifluoromethylation via CH activation is now emerging as the latest attraction. Several pioneering examples and their mechanisms are discussed in this review.

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Bibliographische Detailangaben
Veröffentlicht in:	Advanced synthesis & catalysis 2013-03, Vol.355 (4), p.617-626
Hauptverfasser:	Liu, Hui, Gu, Zhenhua, Jiang, Xuefeng
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Attraction Bonding Catalysis copper CH activation palladium Synthesis trifluoromethylation
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Trifluoromethylation meets CH activation: after transition metal‐catalyzed trifluoromethylation became more and more popular, trifluoromethylation via CH activation is now emerging as the latest attraction. Several pioneering examples and their mechanisms are discussed in this review.
ISSN:	1615-4150 1615-4169
DOI:	10.1002/adsc.201200764