A Continuous Flow Solution to Achieving Efficient Aerobic Anti-Markovnikov Wacker Oxidation

A Continuous Flow Solution to Achieving Efficient Aerobic Anti-Markovnikov Wacker Oxidation

An aerobic anti‐Markovnikov Wacker oxidation for the flow‐synthesis of arylacetaldehydes is reported. In the process, flow chemistry techniques have provided a means to control and minimise the over‐oxidation of sensitive products. The reaction showed general applicability to various functionalised...

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Veröffentlicht in:Advanced synthesis & catalysis 2013-07, Vol.355 (10), p.1905-1910
Hauptverfasser: Bourne, S. L., Ley, S. V.
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Sprache:eng
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aerobic Wacker oxidation
Catalysis
gas-liquid flow
microreactors
palladium catalysis
tube-in-tube
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container_title Advanced synthesis & catalysis
container_volume 355
creator Bourne, S. L.
Ley, S. V.
description An aerobic anti‐Markovnikov Wacker oxidation for the flow‐synthesis of arylacetaldehydes is reported. In the process, flow chemistry techniques have provided a means to control and minimise the over‐oxidation of sensitive products. The reaction showed general applicability to various functionalised styrenes and provided a process capable of a multi‐gram scale.
doi_str_mv 10.1002/adsc.201300278
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source Wiley Online Library Journals Frontfile Complete
subjects aerobic Wacker oxidation
Catalysis
gas-liquid flow
microreactors
palladium catalysis
tube-in-tube
title A Continuous Flow Solution to Achieving Efficient Aerobic Anti-Markovnikov Wacker Oxidation
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