Effect of CeO sub(2) on the Crystalline Structure of Forsterite Synthesized from Low-Grade Magnesite

The influence of CeO sub(2) on the crystalline structure of forsterite synthesized from low-grade magnesite and natural silica is discussed in this paper. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to study the crystalline structure and microstructure of each specimen,...

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Veröffentlicht in:Refractories and industrial ceramics 2013-11, Vol.54 (4), p.291-294
Hauptverfasser: Luo, Xudong, Qu, Dianli, Xie, Zhipeng, Zhao, Wenyan
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Sprache:eng
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Zusammenfassung:The influence of CeO sub(2) on the crystalline structure of forsterite synthesized from low-grade magnesite and natural silica is discussed in this paper. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to study the crystalline structure and microstructure of each specimen, while X' Pert Plus software was used to determine each specimen's lattice parameters. The bulk density, apparent porosity, water absorption, and cold crushing strength of the specimens were determined in accordance with standards issued by the Ministry. The results show that forsterite can be synthesized from low-grade magnesite and natural silica through solid reaction. The synthesis process is facilitated by addition of the appropriate amount of CeO sub(2). A defect caused by Ce sub(2)O in active magnesia accelerates diffusion of the ions. The results obtained by XRD, SEM, and property analysis show that the optimum addition of CeO sub(2) is 0.8 - 1.2%. The forsterite has a microstructure with a homogeneous grain size, a bulk density of 2.15 - 1.18 g/cm super(3), apparent porosity of 29.5 - 30.1%, water absorption of 13.5 - 14.0%, and cold crushing strength of 13.4 - 14.2 MPa.
ISSN:1083-4877
1573-9139
DOI:10.1007/s11148-013-9595-6