Reactions of a Zn(I) complex with group 14 azides--formation of zinc azide and zinc hexazene complexes

Reactions of a Zn(I) complex with group 14 azides--formation of zinc azide and zinc hexazene complexes

Two zinc hexazene complexes L2Zn2(l-1,6-R2-N6) (L = HC[C(Me)N-(2,4,6-Me3C6H2)]2; R = Ph (3), Dipp = 2,6-i-Pr2C6H3 (4)), were synthesized by reaction of the Zn(I) complex L2Zn2 (1) with phenyl azide and 2,6-diisopropylphenyl azide, respectively. 3 represents the second structurally characterized tran...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (8), p.927-929
Hauptverfasser: Gondzik, S, Schulz, S, Bläser, D, Wölper, C, Haack, R, Jansen, G
Format: Artikel
Sprache:eng
Schlagworte:
Dipping
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Zusammenfassung:Two zinc hexazene complexes L2Zn2(l-1,6-R2-N6) (L = HC[C(Me)N-(2,4,6-Me3C6H2)]2; R = Ph (3), Dipp = 2,6-i-Pr2C6H3 (4)), were synthesized by reaction of the Zn(I) complex L2Zn2 (1) with phenyl azide and 2,6-diisopropylphenyl azide, respectively. 3 represents the second structurally characterized transition metal hexazene complex. In contrast, reactions of 1 with Me3MN3 (M = Si, Sn) yielded the azido complex [LZn(l-N3)]2 (2) and Me3M-MMe3.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47687a