Synthesis and Spectral Characterisation of Lanthanide(III) Complexes of Trimethoprim

Synthesis and Spectral Characterisation of Lanthanide(III) Complexes of Trimethoprim

A new series of hepta coordinated lanthanide(III) complexes of the type [ML2Cl3] (where M = LaIII, PrIII, NdIII, SmIII, GdIII, TbIII, DyIII or YIII, L = trimethoprim) have been synthesised. The new complexes were characterised using various physico-chemical methods such as elemental analysis, spectr...

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Veröffentlicht in:Journal of chemical research 2004-03, Vol.2004 (3), p.200-202
Hauptverfasser: Karthikeyan, G, Raj, K Mohan, Elango, K P, Kumar, K Girish
Format: Artikel
Sprache:eng
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Diffraction
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Zusammenfassung:A new series of hepta coordinated lanthanide(III) complexes of the type [ML2Cl3] (where M = LaIII, PrIII, NdIII, SmIII, GdIII, TbIII, DyIII or YIII, L = trimethoprim) have been synthesised. The new complexes were characterised using various physico-chemical methods such as elemental analysis, spectral (IR, UV-VIS, 1H NMR), magnetic and X-ray diffraction analysis. A monocapped trigonal prism structure has been tentatively proposed for the complexes.
ISSN:1747-5198
2047-6507
DOI:10.3184/0308234041640780