Di-μ-hydroxido-κ(4) O:O-di-μ-perchlorato-κ(4) O:O'-bis-[(2,2'-bi-pyridine-κ(2) N,N')copper(II)]

In the title binuclear copper(II) complex, [Cu2(ClO4)2(OH)2(C10H8N2)2], the Cu(II) ion is coordinated in the form of a Jahn-Teller distorted octahedron by two bi-pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa-hedral geometry. The mol-ecule belongs...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-10, Vol.69 (Pt 11), p.m600-m600
Hauptverfasser: Saravanan, B, Jayamani, A, Sengottuvelan, N, Chakkaravarthi, G, Manivannan, V
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title binuclear copper(II) complex, [Cu2(ClO4)2(OH)2(C10H8N2)2], the Cu(II) ion is coordinated in the form of a Jahn-Teller distorted octahedron by two bi-pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa-hedral geometry. The mol-ecule belongs to the symmetry point group C 2h . The Cu(II) ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear mol-ecule, the Cu⋯Cu separation is 2.8614 (7) Å. The crystal structure exhibits O-H⋯O, C-H⋯O and π-π [centroid-centroid distance = 3.5374 (13) Å] inter-actions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813027852