Picosecond kinetics of cytochromes b sub(5) and c

Ligand photolysis and subsequent recombination in cytochromes b sub(5) and c have been studied with picosecond resolution. After photolysis, the formation and recombination of the geminate contact pair are attributed to simple low amplitude ligand bond rotations, a result that can be applied to gemi...

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Veröffentlicht in:The Journal of biological chemistry 1988-01, Vol.263 (13), p.6027-6030
Hauptverfasser: Jongeward, KA, Magde, D, Taube, D J, Traylor, T G
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Sprache:eng
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Zusammenfassung:Ligand photolysis and subsequent recombination in cytochromes b sub(5) and c have been studied with picosecond resolution. After photolysis, the formation and recombination of the geminate contact pair are attributed to simple low amplitude ligand bond rotations, a result that can be applied to geminate processes in other hemoproteins and model heme compounds as well.
ISSN:0021-9258