Poly(ethylene glycol) Stabilized Mesoporous Metal-Organic Framework Nanocrystals: Efficient and Durable Catalysts for the Oxidation of Benzyl Alcohol

Active, selective, and stable: The fabrication of uniform mesoporous Cu3(BTC)2 (BTC: 1,3,5‐benzenetricarboxylate) nanocrystals with tunable size and porosity is reported. The as‐synthesized Cu3(BTC)2 structures show high activity, selectivity, and stability for the aerobic oxidation of benzyl alcoho...

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Veröffentlicht in:	Chemphyschem 2014-01, Vol.15 (1), p.85-89
Hauptverfasser:	Xue, Zhimin, Zhang, Jianling, Peng, Li, Han, Buxing, Mu, Tiancheng, Li, Jianshen, Yang, Guanying
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohol oxidation Catalysis catalysts Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry mesoporous materials metal-organic frameworks nanocrystals Porous materials Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Active, selective, and stable: The fabrication of uniform mesoporous Cu3(BTC)2 (BTC: 1,3,5‐benzenetricarboxylate) nanocrystals with tunable size and porosity is reported. The as‐synthesized Cu3(BTC)2 structures show high activity, selectivity, and stability for the aerobic oxidation of benzyl alcohol to aldehyde.
ISSN:	1439-4235 1439-7641
DOI:	10.1002/cphc.201300809