In Situ Construction of a Coordination Zirconocene Tetrahedron

The current study describes the first in situ synthesis and characterization of a new family of cationic coordination tetrahedra of both the V4F4 and V4E6 type, which are constructed by a new building block based on a trinuclear zirconocene moiety and the dicarboxylate or tricarboxylate anions.

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Veröffentlicht in:Inorganic chemistry 2013-12, Vol.52 (24), p.13815-13817
Hauptverfasser: Liu, Guoliang, Ju, Zhanfeng, Yuan, Daqiang, Hong, Maochun
Format: Artikel
Sprache:eng
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Zusammenfassung:The current study describes the first in situ synthesis and characterization of a new family of cationic coordination tetrahedra of both the V4F4 and V4E6 type, which are constructed by a new building block based on a trinuclear zirconocene moiety and the dicarboxylate or tricarboxylate anions.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic402428m