Electrochemically shape-controlled synthesis in deep eutectic solvents: triambic icosahedral platinum nanocrystals with high-index facets and their enhanced catalytic activity

Pt triambic icosahedral nanocrystals (TIH NCs) enclosed by {771} high-index facets were successfully synthesized electrochemically, for the first time, in ChCl-urea based deep eutectic solvents, and exhibited higher electrocatalytic activity and stability towards ethanol electrooxidation than a comm...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-12, Vol.49 (95), p.11152-11154
Hauptverfasser: Wei, Lu, Zhou, Zhi-You, Chen, Sheng-Pei, Xu, Chang-Deng, Su, Dangsheng, Schuster, Manfred Erwin, Sun, Shi-Gang
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Sprache:eng
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Zusammenfassung:Pt triambic icosahedral nanocrystals (TIH NCs) enclosed by {771} high-index facets were successfully synthesized electrochemically, for the first time, in ChCl-urea based deep eutectic solvents, and exhibited higher electrocatalytic activity and stability towards ethanol electrooxidation than a commercial Pt black catalyst.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46473c