Synthesis of a neo-confused porphyrin and an unusual dihydroporphyrin derivative

Synthesis of a neo-confused porphyrin and an unusual dihydroporphyrin derivative

MacDonald "2 + 2" condensation of a 1,2'-dipyrrylmethane dialdehyde with a 2,2'-dipyrrylmethane afforded a neo-confused porphyrin in 55% yield. In addition, a novel dihydroporphyrin with two appended pyrrolic units was isolated and structurally characterized.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (68), p.7537-7539
Hauptverfasser: Li, Ruoshi, Ferrence, Gregory M, Lash, Timothy D
Format: Artikel
Sprache:eng
Schlagworte:
Condensing
Cyclization
Models, Molecular
Molecular Structure
Porphyrins - chemical synthesis
Porphyrins - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:MacDonald "2 + 2" condensation of a 1,2'-dipyrrylmethane dialdehyde with a 2,2'-dipyrrylmethane afforded a neo-confused porphyrin in 55% yield. In addition, a novel dihydroporphyrin with two appended pyrrolic units was isolated and structurally characterized.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc44248a