Quantification of chemical erosion in the DIII-D divertor and implications for ITER

The Porous Plug Injector (PPI) has proven to be an invaluable diagnostic for in situ characterization and quantification of erosion phenomena in DIII-D. Previous work has led to derivation of three primary figures of merit for chemical erosion (CE) in attached and cold divertor conditions: relative intensity of C+ chemical and physical sources, the CE yield (Ychem), and effective photon efficiencies for chemically eroded products. Application of these figures for accounting of observed absolutely calibrated CI and CII emission intensities is demonstrated to produce a self-consistent solution at the DIII-D targets. Reinterpretation of the CI (C0) spectral lineshape profile supports the relative roles of local chemical versus physical sputtering as previously determined for CII (C+). Comparison of calculated in situ Ychem to that measured ex situ suggests a tokamak-specific lower energy threshold for CE and has potentially major implications for prediction of tritium co-deposition near the divertor targets in ITER.