A molybdenum diphosphonate network structure exhibiting reversible dehydration and selective uptake of methanol

A molybdenum diphosphonate network structure exhibiting reversible dehydration and selective uptake of methanol

A new molybdenum diphosphonate network structure has been prepared and structurally characterised. It shows reversible dehydration, which occurs with a structural change. The dehydrated material is able to adsorb methanol but not ethanol.

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Bibliographische Detailangaben
Veröffentlicht in:CrystEngComm 2013-01, Vol.15 (45), p.9301-9303
Hauptverfasser: Ayi, Ayi A., Burrows, Andrew D., Mahon, Mary F., Sebestyen, Viorica M.
Format: Artikel
Sprache:eng
Schlagworte:
Dehydration
Ethanol
Ethyl alcohol
Materials selection
Methyl alcohol
Molybdenum
Networks
Uptakes
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Beschreibung
Zusammenfassung:A new molybdenum diphosphonate network structure has been prepared and structurally characterised. It shows reversible dehydration, which occurs with a structural change. The dehydrated material is able to adsorb methanol but not ethanol.
ISSN:1466-8033
1466-8033
DOI:10.1039/c3ce40484f