A Study on Vibrational Spectra of PH3 and NF3: An Algebraic Approach

A Study on Vibrational Spectra of PH3 and NF3: An Algebraic Approach

With the new theoretical approach i.e. lie algebraic approach, we have calculated the infrared spectra of Phosphine in the range from 3000 cm super(-) super(1) to 9500 cm super(-) super(1) and Nitrogen Trifluoride in the range from 900 cm super(-) super(1) to 4500 cm super(-) super(1). The model Ham...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Open journal of microphysics 2013-05, Vol.3 (2), p.47-51
Hauptverfasser: Karumuri, S. R., Srinivas, G., Jaliparthi, Vijayasekhar, Babu, K. Sunil, Kumar, V. Sundara Siva, Hanumaiah, A.
Format: Artikel
Sprache:eng
Schlagworte:
Algebra
Construction
Lie groups
Mathematical models
Microphysics
Phosphines
Stretching
Vibrational spectra
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:With the new theoretical approach i.e. lie algebraic approach, we have calculated the infrared spectra of Phosphine in the range from 3000 cm super(-) super(1) to 9500 cm super(-) super(1) and Nitrogen Trifluoride in the range from 900 cm super(-) super(1) to 4500 cm super(-) super(1). The model Hamiltonian, so constructed, seems to describe the P-H and N-F stretching modes accurately with only four numbers of parameters.
ISSN:2162-2450
2162-2469
DOI:10.4236/ojm.2013.32009