A novel membrane reactor for separating hydrogen and oxygen in photocatalytic water splitting

The Z-scheme of water splitting is comprised of H2-photocatalyst and O2-photocatalyst with aid of electron transfer mediator to produce hydrogen and oxygen, respectively. A twin reactor uses a membrane to divide two compartments resulting in the separation of H2 and O 2 simultaneously. [Display omitted] ► Water splitting is performed in a membrane reactor to produce H 2 and O 2 discretely. ► Pt/SrTiO 3:Rh and BiVO 4 are used as the H 2 and the O 2 photocatalysts, respectively. ► The resistance of the membrane does not retard the photoreaction in the reactor. ► We found the H 2-generating of the twin-reactor system was the rate-limiting side. The Z-scheme of water splitting is comprised of H 2-photocatalyst and O 2-photocatalyst with aid of electron transfer mediator to produce hydrogen and oxygen, respectively. A twin reactor, which divided H 2-photocatalyst and O 2-photocatalyst in two compartments using a membrane, can separate H 2 and O 2 thus preventing backward reaction. Pt/SrTiO 3:Rh and BiVO 4 were used as the H 2-photocatalyst and the O 2-photocatalyst, respectively. The diffusion of electron mediator, Fe 2+/Fe 3+, through Nafion membrane was investigated. The transfer rate of mediator ions was remarkably larger than the photoreaction rate, indicating that membrane did not delay the water-splitting reaction in the twin reactor. Under the favorable condition, the hydrogen generation rate reached 0.65 μmol/g h and matched the H 2/O 2stoichiometric ratio of water splitting. We found that the generation of H 2in the twin-reactor system was the rate-limiting step of the water-splitting reaction. By using the twin reactor, the deactivation of Pt/SrTiO 3:Rh could be minimized due to the suppression of Fe(OH) 3formation on the photocatalyst surface.