Oxygen permeation study and improvement of Ba0.5Sr0.5Co0.8Fe0.2Ox perovskite ceramic membranes

Ba0.5Sr0.5Co0.8Fe0.2Ox (BSCF) is a promising mixed conducting material with high oxygen permeability, and is a good candidate for membrane reactors in air separation and catalytic conversion of CH4. To determine the factors impacting oxygen permeation through the BSCF membrane, Pt, Ag catalysts were coated on the membrane surface using photolithography and electron beam evaporation. The coated catalysts did not increase the oxygen flux of BSCF within the studied thickness range. However, the oxygen flux increased as the thickness of the membrane decreased. To further enhance the oxygen flux, a BSCF membrane with asymmetric geometry was prepared by dry pressing. The effects of the porous substrate and the dense thin layer on the performance of the BSCF asymmetric membrane were studied. The oxygen flux increased as the thickness of thin dense layer decreased. The porous substrate still appears to exert a resistance on the oxygen permeation through the membrane.