Amine formylation via carbon dioxide recycling catalyzed by a simple and efficient heterogeneous palladium catalyst

A simple and efficient Pd/Al2O3-NR-RD catalyst was prepared by depositing palladium on a shape controllable Al2O3-NR support through a two-step process that involves hydrothermal synthesis of Al2O3-NRs followed by reductive-deposition of palladium. This catalyst showed high activity in the catalytic...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (2), p.189-191
Hauptverfasser: Cui, Xinjiang, Zhang, Yan, Deng, Youquan, Shi, Feng
Format: Artikel
Sprache:eng
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Zusammenfassung:A simple and efficient Pd/Al2O3-NR-RD catalyst was prepared by depositing palladium on a shape controllable Al2O3-NR support through a two-step process that involves hydrothermal synthesis of Al2O3-NRs followed by reductive-deposition of palladium. This catalyst showed high activity in the catalytic formylation of amines by CO2-H2 under mild conditions with up to 96% yield.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46427j