Disproportionation of Achiral Nickel(II) Centers into Two Kinds of Chiral Nickel(II) Centers Caused by an Achiral Diimine Ligand

Chiral creation: A disproportionation reaction, in which achiral square‐planar NiII centers are converted into two kinds of chiral, octahedral NiII centers on treatment with an achiral diimine ligand, was discovered in a D‐penicillaminato AuINiII coordination system, presenting a unique method for g...

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Veröffentlicht in:	Chemistry : a European journal 2013-12, Vol.19 (49), p.16532-16536
Hauptverfasser:	Igashira-Kamiyama, Asako, Fukushima, Akeha, Konno, Takumi
Format:	Artikel
Sprache:	eng
Schlagworte:	amino acids Amino Acids - chemistry Chemistry chirality coordination chemistry Coordination Complexes - chemistry heterometallic complexes Imines - chemistry Ligands Models, Molecular Nickel - chemistry Stereoisomerism S ligands
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Beschreibung
Zusammenfassung:	Chiral creation: A disproportionation reaction, in which achiral square‐planar NiII centers are converted into two kinds of chiral, octahedral NiII centers on treatment with an achiral diimine ligand, was discovered in a D‐penicillaminato AuINiII coordination system, presenting a unique method for generating and increasing chiral centers (see scheme).
ISSN:	0947-6539 1521-3765
DOI:	10.1002/chem.201303731