Isomorphs, hidden scale invariance, and quasiuniversality
This paper first establishes an approximate scaling property of the potential-energy function of a classical liquid with good isomorphs (a Roskilde-simple liquid). This "pseudohomogeneous" property makes explicit that-and in which sense-such a system has a hidden scale invariance. The seco...
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Veröffentlicht in: | Physical review. E, Statistical, nonlinear, and soft matter physics Statistical, nonlinear, and soft matter physics, 2013-10, Vol.88 (4), p.042139-042139, Article 042139 |
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Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | This paper first establishes an approximate scaling property of the potential-energy function of a classical liquid with good isomorphs (a Roskilde-simple liquid). This "pseudohomogeneous" property makes explicit that-and in which sense-such a system has a hidden scale invariance. The second part of the paper gives a potential-energy formulation of the quasiuniversality of monatomic Roskilde-simple liquids, which was recently rationalized in terms of the existence of a quasiuniversal single-parameter family of reduced-coordinate constant-potential-energy hypersurfaces [J. C. Dyre, Phys. Rev. E 87, 022106 (2013)]. The new formulation involves a quasiuniversal reduced-coordinate potential-energy function. A few consequences of this are discussed. |
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ISSN: | 1539-3755 1550-2376 |
DOI: | 10.1103/PhysRevE.88.042139 |