Isomorphs, hidden scale invariance, and quasiuniversality

This paper first establishes an approximate scaling property of the potential-energy function of a classical liquid with good isomorphs (a Roskilde-simple liquid). This "pseudohomogeneous" property makes explicit that-and in which sense-such a system has a hidden scale invariance. The seco...

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Veröffentlicht in:Physical review. E, Statistical, nonlinear, and soft matter physics Statistical, nonlinear, and soft matter physics, 2013-10, Vol.88 (4), p.042139-042139, Article 042139
1. Verfasser: Dyre, Jeppe C
Format: Artikel
Sprache:eng
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Zusammenfassung:This paper first establishes an approximate scaling property of the potential-energy function of a classical liquid with good isomorphs (a Roskilde-simple liquid). This "pseudohomogeneous" property makes explicit that-and in which sense-such a system has a hidden scale invariance. The second part of the paper gives a potential-energy formulation of the quasiuniversality of monatomic Roskilde-simple liquids, which was recently rationalized in terms of the existence of a quasiuniversal single-parameter family of reduced-coordinate constant-potential-energy hypersurfaces [J. C. Dyre, Phys. Rev. E 87, 022106 (2013)]. The new formulation involves a quasiuniversal reduced-coordinate potential-energy function. A few consequences of this are discussed.
ISSN:1539-3755
1550-2376
DOI:10.1103/PhysRevE.88.042139