Relative retention times of chlorinated monoterpenes
GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1...
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Veröffentlicht in: | Chemosphere (Oxford) 2000-08, Vol.41 (4), p.467-472 |
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description | GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1 chlorinated camphene. Useful correlations between structure and retention time were found. Similar changes in structure for different compounds lead to similar changes in retention times. These correlations allow to predict retention times for yet unknown Toxaphene congeners. |
doi_str_mv | 10.1016/S0045-6535(99)00477-4 |
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They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1 chlorinated camphene. Useful correlations between structure and retention time were found. Similar changes in structure for different compounds lead to similar changes in retention times. These correlations allow to predict retention times for yet unknown Toxaphene congeners.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/S0045-6535(99)00477-4</identifier><identifier>PMID: 10819215</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>chlorinated bornances ; chlorinated bornenes ; chlorinated camphene ; chlorinated dihydrocamphenes ; Chlorinated terpenes ; Chlorine Compounds - analysis ; Chlorine Compounds - chemistry ; Chromatography, Gas ; congeners ; Environmental Monitoring ; gas chromatography ; Insecticides - analysis ; Insecticides - chemistry ; organochlorine compounds ; Retention times ; Structure-Activity Relationship ; Structure-behavior correlations ; Terpenes - analysis ; Terpenes - chemistry ; Toxaphene ; Toxaphene - analysis ; Toxaphene - chemistry</subject><ispartof>Chemosphere (Oxford), 2000-08, Vol.41 (4), p.467-472</ispartof><rights>2000 Elsevier Science Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c416t-b5a6f7876eaf856d3571a261e53a262a4e792b59c06eb28d5ec6f04e9ff108b33</citedby><cites>FETCH-LOGICAL-c416t-b5a6f7876eaf856d3571a261e53a262a4e792b59c06eb28d5ec6f04e9ff108b33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0045-6535(99)00477-4$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/10819215$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nikiforov, Vladimir A.</creatorcontrib><creatorcontrib>Karavan, Vladimir A.</creatorcontrib><creatorcontrib>Miltsov, Sergei A.</creatorcontrib><title>Relative retention times of chlorinated monoterpenes</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1 chlorinated camphene. Useful correlations between structure and retention time were found. Similar changes in structure for different compounds lead to similar changes in retention times. These correlations allow to predict retention times for yet unknown Toxaphene congeners.</description><subject>chlorinated bornances</subject><subject>chlorinated bornenes</subject><subject>chlorinated camphene</subject><subject>chlorinated dihydrocamphenes</subject><subject>Chlorinated terpenes</subject><subject>Chlorine Compounds - analysis</subject><subject>Chlorine Compounds - chemistry</subject><subject>Chromatography, Gas</subject><subject>congeners</subject><subject>Environmental Monitoring</subject><subject>gas chromatography</subject><subject>Insecticides - analysis</subject><subject>Insecticides - chemistry</subject><subject>organochlorine compounds</subject><subject>Retention times</subject><subject>Structure-Activity Relationship</subject><subject>Structure-behavior correlations</subject><subject>Terpenes - analysis</subject><subject>Terpenes - chemistry</subject><subject>Toxaphene</subject><subject>Toxaphene - analysis</subject><subject>Toxaphene - chemistry</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkE1LxDAQhoMo7rr6E9SeRA_VJG2S5iQifoEgqHsOaTrRSNusSXbBf293K-LN08vA884MD0KHBJ8TTPjFC8Ylyzkr2KmUZ8MgRF5uoSmphMwJldU2mv4iE7QX4wfGQ5HJXTQhuCKSEjZF5TO0OrkVZAES9Mn5Pkuug5h5m5n31gfX6wRN1vneJwgL6CHuox2r2wgHPzlD89ub1-v7_PHp7uH66jE3JeEpr5nmVlSCg7YV403BBNGUE2DFEFSXICStmTSYQ02rhoHhFpcgrR0erItihk7GvYvgP5cQk-pcNNC2uge_jIqUjDEh1yAbQRN8jAGsWgTX6fClCFZrXWqjS61dKCnVRpcqh97Rz4Fl3UHzpzX6GYDjEbDaK_0WXFTzF4pJgalkFAs6EJcjAYOIlYOgonHQG2hcAJNU490_T3wDg2KC1w</recordid><startdate>20000801</startdate><enddate>20000801</enddate><creator>Nikiforov, Vladimir A.</creator><creator>Karavan, Vladimir A.</creator><creator>Miltsov, Sergei A.</creator><general>Elsevier Ltd</general><scope>FBQ</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope></search><sort><creationdate>20000801</creationdate><title>Relative retention times of chlorinated monoterpenes</title><author>Nikiforov, Vladimir A. ; Karavan, Vladimir A. ; Miltsov, Sergei A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c416t-b5a6f7876eaf856d3571a261e53a262a4e792b59c06eb28d5ec6f04e9ff108b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>chlorinated bornances</topic><topic>chlorinated bornenes</topic><topic>chlorinated camphene</topic><topic>chlorinated dihydrocamphenes</topic><topic>Chlorinated terpenes</topic><topic>Chlorine Compounds - analysis</topic><topic>Chlorine Compounds - chemistry</topic><topic>Chromatography, Gas</topic><topic>congeners</topic><topic>Environmental Monitoring</topic><topic>gas chromatography</topic><topic>Insecticides - analysis</topic><topic>Insecticides - chemistry</topic><topic>organochlorine compounds</topic><topic>Retention times</topic><topic>Structure-Activity Relationship</topic><topic>Structure-behavior correlations</topic><topic>Terpenes - analysis</topic><topic>Terpenes - chemistry</topic><topic>Toxaphene</topic><topic>Toxaphene - analysis</topic><topic>Toxaphene - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nikiforov, Vladimir A.</creatorcontrib><creatorcontrib>Karavan, Vladimir A.</creatorcontrib><creatorcontrib>Miltsov, Sergei A.</creatorcontrib><collection>AGRIS</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nikiforov, Vladimir A.</au><au>Karavan, Vladimir A.</au><au>Miltsov, Sergei A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Relative retention times of chlorinated monoterpenes</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2000-08-01</date><risdate>2000</risdate><volume>41</volume><issue>4</issue><spage>467</spage><epage>472</epage><pages>467-472</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><abstract>GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1 chlorinated camphene. Useful correlations between structure and retention time were found. Similar changes in structure for different compounds lead to similar changes in retention times. These correlations allow to predict retention times for yet unknown Toxaphene congeners.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>10819215</pmid><doi>10.1016/S0045-6535(99)00477-4</doi><tpages>6</tpages></addata></record> |
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subjects | chlorinated bornances chlorinated bornenes chlorinated camphene chlorinated dihydrocamphenes Chlorinated terpenes Chlorine Compounds - analysis Chlorine Compounds - chemistry Chromatography, Gas congeners Environmental Monitoring gas chromatography Insecticides - analysis Insecticides - chemistry organochlorine compounds Retention times Structure-Activity Relationship Structure-behavior correlations Terpenes - analysis Terpenes - chemistry Toxaphene Toxaphene - analysis Toxaphene - chemistry |
title | Relative retention times of chlorinated monoterpenes |
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