Relative retention times of chlorinated monoterpenes

GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1...

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Veröffentlicht in:Chemosphere (Oxford) 2000-08, Vol.41 (4), p.467-472
Hauptverfasser: Nikiforov, Vladimir A., Karavan, Vladimir A., Miltsov, Sergei A.
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Karavan, Vladimir A.
Miltsov, Sergei A.
description GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1 chlorinated camphene. Useful correlations between structure and retention time were found. Similar changes in structure for different compounds lead to similar changes in retention times. These correlations allow to predict retention times for yet unknown Toxaphene congeners.
doi_str_mv 10.1016/S0045-6535(99)00477-4
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subjects chlorinated bornances
chlorinated bornenes
chlorinated camphene
chlorinated dihydrocamphenes
Chlorinated terpenes
Chlorine Compounds - analysis
Chlorine Compounds - chemistry
Chromatography, Gas
congeners
Environmental Monitoring
gas chromatography
Insecticides - analysis
Insecticides - chemistry
organochlorine compounds
Retention times
Structure-Activity Relationship
Structure-behavior correlations
Terpenes - analysis
Terpenes - chemistry
Toxaphene
Toxaphene - analysis
Toxaphene - chemistry
title Relative retention times of chlorinated monoterpenes
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