Relative retention times of chlorinated monoterpenes

GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1...

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Veröffentlicht in:	Chemosphere (Oxford) 2000-08, Vol.41 (4), p.467-472
Hauptverfasser:	Nikiforov, Vladimir A., Karavan, Vladimir A., Miltsov, Sergei A.
Format:	Artikel
Sprache:	eng
Schlagworte:	chlorinated bornances chlorinated bornenes chlorinated camphene chlorinated dihydrocamphenes Chlorinated terpenes Chlorine Compounds - analysis Chlorine Compounds - chemistry Chromatography, Gas congeners Environmental Monitoring gas chromatography Insecticides - analysis Insecticides - chemistry organochlorine compounds Retention times Structure-Activity Relationship Structure-behavior correlations Terpenes - analysis Terpenes - chemistry Toxaphene Toxaphene - analysis Toxaphene - chemistry
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Zusammenfassung:	GC retention times for 67 chlorinated monoterpenes, belonging to the technical pesticide Toxaphene have been measured under the same conditions and relative retention times have been determined. They consisted of 45 chlorinated bornanes, 13 chlorinated bornenes, 8 chlorinated dihydrocamphenes and 1 chlorinated camphene. Useful correlations between structure and retention time were found. Similar changes in structure for different compounds lead to similar changes in retention times. These correlations allow to predict retention times for yet unknown Toxaphene congeners.
ISSN:	0045-6535 1879-1298
DOI:	10.1016/S0045-6535(99)00477-4