Potential of Presep® PolyChelate as a Chelating Resin: Comparative Study with Some Aminocarboxylic Acid-type Resins

The potential of Presep® PolyChelate as a chelating resin was studied in detail. The chelating resin with extraction capacity for Cu of 0.30 mmol L−1 could quantitatively extract Cd, Co, Cu, Fe, Mo, Ni, Pb, V, and Zn at pH 4 or 5.5; however, only very scant amounts of Na, K, Mg, and Ca were captured...

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Veröffentlicht in:Analytical Sciences 2013/11/10, Vol.29(11), pp.1107-1112
Hauptverfasser: KAGAYA, Shigehiro, SAEKI, Yumi, MORISHIMA, Daiki, SHIROTA, Riko, KAJIWARA, Takehiro, KATO, Toshifumi, GEMMEI-IDE, Makoto
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Sprache:eng
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Zusammenfassung:The potential of Presep® PolyChelate as a chelating resin was studied in detail. The chelating resin with extraction capacity for Cu of 0.30 mmol L−1 could quantitatively extract Cd, Co, Cu, Fe, Mo, Ni, Pb, V, and Zn at pH 4 or 5.5; however, only very scant amounts of Na, K, Mg, and Ca were captured at pH levels below 7. The quantitative extraction could be achieved in 100 – 1000 mL of artificial seawater and at a flow rate of 3 – 30 mL min−1. The performance of Presep® PolyChelate was compared to the other aminocarboxylic acid-type chelating resins, including Nobias Chelate-PA1, Chelex 100, Muromac B-1, Lewatit TP 207, and NTA Superflow, under the same conditions. The solid-phase extraction of the nine elements in the certified reference material (ES-L-1, ground water) and a commercially available table salt was also demonstrated.
ISSN:0910-6340
1348-2246
DOI:10.2116/analsci.29.1107