A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C-C bond formation

The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, wit...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (85), p.9917-9919
Hauptverfasser:	Miyamura, Hiroyuki, Choo, Gerald C Y, Yasukawa, Tomohiro, Yoo, Woo-Jin, Kobayashi, Shu
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Bimetals Bonding Carbon-carbon composites Catalysts Michael reaction Nanoparticles Synthesis
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creator	Miyamura, Hiroyuki Choo, Gerald C Y Yasukawa, Tomohiro Yoo, Woo-Jin Kobayashi, Shu
description	The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, within the chiral composite material, is crucial for catalytic activity.
doi_str_mv	10.1039/c3cc46204h
format	Article
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Asymmetry Bimetals Bonding Carbon-carbon composites Catalysts Michael reaction Nanoparticles Synthesis
title	A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C-C bond formation
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