A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C-C bond formation
The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, wit...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (85), p.9917-9919 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, within the chiral composite material, is crucial for catalytic activity. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c3cc46204h |