The Kinetics and Isotherms of Adsorption of Sb(III) from Aqueous Solutions onto the Porous Biomorph-Genetic Composite of Fe2O3/Fe3O4/C with Bamboo Template

Static adsorption of Sb (III) on a porous biomorph-genetic composite of Fe2O3/Fe3O4/C (PBGC-Fe/C-B) was studied. The results showed that the kinetic curve of Sb (III) adsorption by PBGC-Fe/C-B had same change trend under initial concentration of 5, 10 and 50 mg/L. The fitting and regression analysis...

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Veröffentlicht in:Applied Mechanics and Materials 2013-09, Vol.394 (Mechatronics, Applied Mechanics and Energy Engineering), p.8-13
Hauptverfasser: Zhu, Yi Nian, Zhu, Zong Qiang, Wei, Wen Hui, Cao, Shuang
Format: Artikel
Sprache:eng
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Zusammenfassung:Static adsorption of Sb (III) on a porous biomorph-genetic composite of Fe2O3/Fe3O4/C (PBGC-Fe/C-B) was studied. The results showed that the kinetic curve of Sb (III) adsorption by PBGC-Fe/C-B had same change trend under initial concentration of 5, 10 and 50 mg/L. The fitting and regression analysis of four kinds of kinetic model indicated that, the adsorption kinetics of Sb (III) by the PBGC-Fe/C-B well follow the pseudo-second-order model (R2>0.9999). At different reaction temperature (25 °C, 35 °C and 45 °C), the adsorption capacity of Sb (III) by PBGC-Fe/C-B both increased with increasing the solution equilibrium concentration. While it showed a declined tendency with temperature increased. The Langmuir isotherm model (R2>0.98) and the Freundlich isotherm model (R2>0.95) had both better fitted with the equilibrium data.
ISSN:1660-9336
1662-7482
1662-7482
DOI:10.4028/www.scientific.net/AMM.394.8