Optical activity in sub-wavelength metallic grids and fishnet metamaterials in the conical mount

We report on measurements of optical activity in reflection in the conical mount from two plasmonically resonant nanostructures; a sub-wavelength silver meshed grid and a fishnet metamaterial. The square-centimeter size of the materials, formed by nano-imprint lithography, allows reliable investigation of such materials by plane-wave techniques with minimal focusing. For both materials we observe strong polarization conversion (s-to p-polarization, and vice versa) in generalized ellipsometry measurements. We compared the spectra to analytical predictions using surface plasmon polariton (SPP) theory and find good agreement for the meshed grid. The spectra for the meshed grid are also well modeled using the rigorous coupled wave analysis (RCWA) technique. Simulated results for the more conplicated fishnet layer showing qualitative agreement are also presented. We then probe the validity of describing the observations using homogenous parameters such as dichroismand birefringence, by examining the calculated reflection of nominally polarized incident light using simulated and measured Mueller matrices. The results show that the cross-polarization that we observe is primarily related to linear birefringence and dichroism, although circular effects are indeed present.