Orientational variation, solvate composition and molecular flexibility in well-ordered cocrystals of the fullerene C70 with bis(ethylenedithio)tetrathiafulvalene

Cocrystallization of C70 with bis(ethylenedithio)tetrathiafulvalene (ET) produces two different solvates, C70·ET·C6H6 and 2C70·2ET·CS2, which show distinctly different overlap between the fullerene and ET molecules.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-11, Vol.49 (91), p.10721-10723
Hauptverfasser: Ghiassi, Kamran B, Olmstead, Marilyn M, Balch, Alan L
Format: Artikel
Sprache:eng
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Zusammenfassung:Cocrystallization of C70 with bis(ethylenedithio)tetrathiafulvalene (ET) produces two different solvates, C70·ET·C6H6 and 2C70·2ET·CS2, which show distinctly different overlap between the fullerene and ET molecules.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46367b