Copper-Catalyzed Methyl Esterification Reactions via C–C Bond Cleavage

Copper-Catalyzed Methyl Esterification Reactions via C–C Bond Cleavage

The highly effective synthesis of methyl esters from benzylic alcohols, aldehydes, or acids via copper-catalyzed C–C cleavage from tert-butyl hydroperoxide is reported in this paper for the first time. Our protocol is easily accessible and practical, making it a possible supplement for the tradition...

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Veröffentlicht in:Journal of organic chemistry 2013-10, Vol.78 (19), p.9898-9905
Hauptverfasser: Zhu, Yan, Yan, Hong, Lu, Linhua, Liu, Defu, Rong, Guangwei, Mao, Jincheng
Format: Artikel
Sprache:eng
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Zusammenfassung:The highly effective synthesis of methyl esters from benzylic alcohols, aldehydes, or acids via copper-catalyzed C–C cleavage from tert-butyl hydroperoxide is reported in this paper for the first time. Our protocol is easily accessible and practical, making it a possible supplement for the traditional way.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo4016387