Iridium(I)-catalyzed vinylic C-H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron

Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (68), p.7546-7548
Hauptverfasser:	Sasaki, Ikuo, Doi, Hana, Hashimoto, Toshiya, Kikuchi, Takao, Ito, Hajime, Ishiyama, Tatsuo
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron Compounds - chemical synthesis Boron Compounds - chemistry Carboxylic Acids - chemistry Catalysis Derivatives Functional groups Iridium - chemistry Molecular Structure Organometallic Compounds - chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c3cc44149k