Dicopper(II/II) complexes of an amine phenol hexadentate ligand showing ?-bis(tridentate) coordination: EPR spectral model of binuclear CuA centre of nitrous oxide reductase

Dicopper(II/II) complexes of an amine phenol hexadentate ligand showing ?-bis(tridentate) coordination: EPR spectral model of binuclear CuA centre of nitrous oxide reductase

A new family of binuclear Cu(II)-Cu(II) complexes with a hexadentate Schiff base ligand containing imine-phenol end groups has been studied as an EPR spectral model of the binuclear CuA centre of nitrous oxide reductase. The complexes have been characterised by elemental analysis, solution electrica...

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Veröffentlicht in:Journal of chemical research 2004-08, Vol.2004 (8), p.541-544
Hauptverfasser: Bera, Manindranath, Mahato, Debashis Sanjit Kumar
Format: Artikel
Sprache:eng
Schlagworte:
Electrical resistivity
Infrared radiation
Ligands
Nitrous oxides
Optimization
Reductases
Resistivity
Spectra
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Zusammenfassung:A new family of binuclear Cu(II)-Cu(II) complexes with a hexadentate Schiff base ligand containing imine-phenol end groups has been studied as an EPR spectral model of the binuclear CuA centre of nitrous oxide reductase. The complexes have been characterised by elemental analysis, solution electrical conductivities, IR, UV-vis, EPR spectral, magnetic studies and geometrical optimisation by molecular mechanics (MM2) method.
ISSN:1747-5198
2047-6507
DOI:10.3184/0308234042563857