Morphology and thermal and mechanical properties of phosphonium vermiculite filled poly(ethylene terephthalate) composites
A series of poly(ethylene terephthalate) (PET)/phosphonium vermiculite (P‐VMT) composites were prepared by a melt‐blending method, and we investigated the morphology and thermal and mechanical properties of the composites. We prepared P‐VMT with quaternary phosphonium salts using the common method f...
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| Veröffentlicht in: | Journal of applied polymer science 2012-10, Vol.126 (2), p.601-607 |
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| creator | Zeng, Xianshen Cai, Deming Lin, Zhidan Cai, Xiang Zhang, Xiuju Tan, Shaozao Xu, Yingbin |
| description | A series of poly(ethylene terephthalate) (PET)/phosphonium vermiculite (P‐VMT) composites were prepared by a melt‐blending method, and we investigated the morphology and thermal and mechanical properties of the composites. We prepared P‐VMT with quaternary phosphonium salts using the common method followed by a cation‐exchange reaction. X‐ray diffraction showed that the phosphonium surfactants were partially intercalated into the vermiculite layers, The d‐spacing of the PET–clay sample was somewhat less than that of the P‐VMT because some degradation of the surfactant took place during melt processing. Compared with PET, the PET–clay composites had a lower decomposition temperature and showed a 17.4% increase in the tensile strength with a P‐VMT content of 3 wt %. Scanning electron microscopy and transmission electron microscopy demonstrated that P‐VMT had a homogeneous dispersion and good compatibility in the polymer matrix with a low content of additive and indicated that the P‐VMT content of 3 wt % was optimal. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 |
| doi_str_mv | 10.1002/app.36553 |
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We prepared P‐VMT with quaternary phosphonium salts using the common method followed by a cation‐exchange reaction. X‐ray diffraction showed that the phosphonium surfactants were partially intercalated into the vermiculite layers, The d‐spacing of the PET–clay sample was somewhat less than that of the P‐VMT because some degradation of the surfactant took place during melt processing. Compared with PET, the PET–clay composites had a lower decomposition temperature and showed a 17.4% increase in the tensile strength with a P‐VMT content of 3 wt %. Scanning electron microscopy and transmission electron microscopy demonstrated that P‐VMT had a homogeneous dispersion and good compatibility in the polymer matrix with a low content of additive and indicated that the P‐VMT content of 3 wt % was optimal. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.36553</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; Materials science ; Mechanical properties ; Morphology ; organoclay ; polyesters ; Polyethylene terephthalates ; Polymer industry, paints, wood ; Polymers ; Reproduction ; Scanning electron microscopy ; Surfactants ; Technology of polymers ; Terephthalate ; Vermiculite</subject><ispartof>Journal of applied polymer science, 2012-10, Vol.126 (2), p.601-607</ispartof><rights>Copyright © 2012 Wiley Periodicals, Inc.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4353-1eebfec4b69e10249b86acebe24c7ccfcf8441b17238e016e946f9bc81ea12da3</citedby><cites>FETCH-LOGICAL-c4353-1eebfec4b69e10249b86acebe24c7ccfcf8441b17238e016e946f9bc81ea12da3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.36553$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.36553$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26176954$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zeng, Xianshen</creatorcontrib><creatorcontrib>Cai, Deming</creatorcontrib><creatorcontrib>Lin, Zhidan</creatorcontrib><creatorcontrib>Cai, Xiang</creatorcontrib><creatorcontrib>Zhang, Xiuju</creatorcontrib><creatorcontrib>Tan, Shaozao</creatorcontrib><creatorcontrib>Xu, Yingbin</creatorcontrib><title>Morphology and thermal and mechanical properties of phosphonium vermiculite filled poly(ethylene terephthalate) composites</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>A series of poly(ethylene terephthalate) (PET)/phosphonium vermiculite (P‐VMT) composites were prepared by a melt‐blending method, and we investigated the morphology and thermal and mechanical properties of the composites. We prepared P‐VMT with quaternary phosphonium salts using the common method followed by a cation‐exchange reaction. X‐ray diffraction showed that the phosphonium surfactants were partially intercalated into the vermiculite layers, The d‐spacing of the PET–clay sample was somewhat less than that of the P‐VMT because some degradation of the surfactant took place during melt processing. Compared with PET, the PET–clay composites had a lower decomposition temperature and showed a 17.4% increase in the tensile strength with a P‐VMT content of 3 wt %. Scanning electron microscopy and transmission electron microscopy demonstrated that P‐VMT had a homogeneous dispersion and good compatibility in the polymer matrix with a low content of additive and indicated that the P‐VMT content of 3 wt % was optimal. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>Morphology</subject><subject>organoclay</subject><subject>polyesters</subject><subject>Polyethylene terephthalates</subject><subject>Polymer industry, paints, wood</subject><subject>Polymers</subject><subject>Reproduction</subject><subject>Scanning electron microscopy</subject><subject>Surfactants</subject><subject>Technology of polymers</subject><subject>Terephthalate</subject><subject>Vermiculite</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kU9vFSEUxSdGE5_Vhd-AxJi0i2lhYBhY1kbbpn_s4qlLwvDuOFRmQJixHT-9tK_tookLAuT-zuFeTlG8J3ifYFwd6BD2Ka9r-qJYESybkvFKvCxWuUZKIWX9uniT0jXGhNSYr4q_Fz6G3jv_c0F63KCphzhod38ewPR6tCZfQ_QB4mQhId-hLEh5jXYe0J_MWzM7OwHqrHOwQcG7ZRemfnEwApogQuinXjs9wR4yfgg-ZTq9LV512iV497DvFN--fF4fnZTnX49Pjw7PS8NoTUsC0HZgWMslEFwx2QquDbRQMdMY05lOMEZa0lRUACYcJOOdbI0goEm10XSn2N365iF-z5AmNdhkwDk9gp-TIozKppK0YRn98Ay99nMcc3eK5F6YaIQQmdrbUib6lCJ0KkQ76LgogtVdCiqnoO5TyOzHB0ed8kd2UY_GpidBxUnDZX338sGWu7EOlv8bqsOrq0fncquwaYLbJ4WOvxRvaFOrH5fH6mR9uT77zi_UJ_oPpIOoog</recordid><startdate>20121015</startdate><enddate>20121015</enddate><creator>Zeng, Xianshen</creator><creator>Cai, Deming</creator><creator>Lin, Zhidan</creator><creator>Cai, Xiang</creator><creator>Zhang, Xiuju</creator><creator>Tan, Shaozao</creator><creator>Xu, Yingbin</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20121015</creationdate><title>Morphology and thermal and mechanical properties of phosphonium vermiculite filled poly(ethylene terephthalate) composites</title><author>Zeng, Xianshen ; Cai, Deming ; Lin, Zhidan ; Cai, Xiang ; Zhang, Xiuju ; Tan, Shaozao ; Xu, Yingbin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4353-1eebfec4b69e10249b86acebe24c7ccfcf8441b17238e016e946f9bc81ea12da3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>Morphology</topic><topic>organoclay</topic><topic>polyesters</topic><topic>Polyethylene terephthalates</topic><topic>Polymer industry, paints, wood</topic><topic>Polymers</topic><topic>Reproduction</topic><topic>Scanning electron microscopy</topic><topic>Surfactants</topic><topic>Technology of polymers</topic><topic>Terephthalate</topic><topic>Vermiculite</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zeng, Xianshen</creatorcontrib><creatorcontrib>Cai, Deming</creatorcontrib><creatorcontrib>Lin, Zhidan</creatorcontrib><creatorcontrib>Cai, Xiang</creatorcontrib><creatorcontrib>Zhang, Xiuju</creatorcontrib><creatorcontrib>Tan, Shaozao</creatorcontrib><creatorcontrib>Xu, Yingbin</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zeng, Xianshen</au><au>Cai, Deming</au><au>Lin, Zhidan</au><au>Cai, Xiang</au><au>Zhang, Xiuju</au><au>Tan, Shaozao</au><au>Xu, Yingbin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Morphology and thermal and mechanical properties of phosphonium vermiculite filled poly(ethylene terephthalate) composites</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2012-10-15</date><risdate>2012</risdate><volume>126</volume><issue>2</issue><spage>601</spage><epage>607</epage><pages>601-607</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>A series of poly(ethylene terephthalate) (PET)/phosphonium vermiculite (P‐VMT) composites were prepared by a melt‐blending method, and we investigated the morphology and thermal and mechanical properties of the composites. We prepared P‐VMT with quaternary phosphonium salts using the common method followed by a cation‐exchange reaction. X‐ray diffraction showed that the phosphonium surfactants were partially intercalated into the vermiculite layers, The d‐spacing of the PET–clay sample was somewhat less than that of the P‐VMT because some degradation of the surfactant took place during melt processing. Compared with PET, the PET–clay composites had a lower decomposition temperature and showed a 17.4% increase in the tensile strength with a P‐VMT content of 3 wt %. Scanning electron microscopy and transmission electron microscopy demonstrated that P‐VMT had a homogeneous dispersion and good compatibility in the polymer matrix with a low content of additive and indicated that the P‐VMT content of 3 wt % was optimal. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.36553</doi><tpages>7</tpages></addata></record> |
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| subjects | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Materials science Mechanical properties Morphology organoclay polyesters Polyethylene terephthalates Polymer industry, paints, wood Polymers Reproduction Scanning electron microscopy Surfactants Technology of polymers Terephthalate Vermiculite |
| title | Morphology and thermal and mechanical properties of phosphonium vermiculite filled poly(ethylene terephthalate) composites |
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