Decarboxylative photooxygenation of arylacetic acids by using mercuric oxide

Decarboxylative photooxygenation of arylacetic acids by using mercuric oxide

A new method for decarboxylative photooxygenation of arylacetic acids is developed by using light sensitive HgO in MeCN-MeOH which leads to aldehydes and ketones in high yield through trapping of benzylic radical intermediates by dioxygen.

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Bibliographische Detailangaben
Veröffentlicht in:Journal of chemical research 2004-04, Vol.2004 (4), p.296-297
Hauptverfasser: Habibi, Mohammad H, Farhadi, Saeid
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes
Ketones
Oxides
Radicals
Trapping
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Beschreibung
Zusammenfassung:A new method for decarboxylative photooxygenation of arylacetic acids is developed by using light sensitive HgO in MeCN-MeOH which leads to aldehydes and ketones in high yield through trapping of benzylic radical intermediates by dioxygen.
ISSN:1747-5198
2047-6507
DOI:10.3184/0308234041209185