Structures and stereochemistries of oscillatoxin B, 31-noroscillatoxin B, oscillatoxin D, and 30-methyloscillatoxin D

Structures and stereochemistries of oscillatoxin B, 31-noroscillatoxin B, oscillatoxin D, and 30-methyloscillatoxin D

Four aplysiatoxin-related compounds, viz., oscillatoxin B, 31-noroscillatoxin B, oscillatoxin D, and 30-methyloscillatoxin D, have been isolated from the marine blue-green alga Lyngbya majuscula (Oscillatoriaceae). The structures and stereochemistries have been determined by spectral studies and che...

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Veröffentlicht in:Journal of organic chemistry 1985-04, Vol.50 (8), p.1255-1259
Hauptverfasser: Entzeroth, Michael, Blackman, Adrian J, Mynderse, Jon S, Moore, Richard E
Format: Artikel
Sprache:eng
Schlagworte:
Biological and medical sciences
Lyngbya majuscula
Medical sciences
Plant poisons toxicology
Toxicology
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Zusammenfassung:Four aplysiatoxin-related compounds, viz., oscillatoxin B, 31-noroscillatoxin B, oscillatoxin D, and 30-methyloscillatoxin D, have been isolated from the marine blue-green alga Lyngbya majuscula (Oscillatoriaceae). The structures and stereochemistries have been determined by spectral studies and chemical degradation. Oscillatoxin B was shown to be a mixture of the C-4 isomers B1 and B2.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo00208a019