Rhodium(iii)-catalyzed ortho-olefination of aryl phosphonates
Rhodium(iii)-catalyzed C-H olefination of aryl phosphonic esters is reported for the first time. In this mild and efficient process, the phosphonic ester group is utilized successfully as a new directing group. In addition, mono-olefination for aryl phosphonates is observed using a phosphonic diamid...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2013-10, Vol.11 (40), p.6879-6882 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Rhodium(iii)-catalyzed C-H olefination of aryl phosphonic esters is reported for the first time. In this mild and efficient process, the phosphonic ester group is utilized successfully as a new directing group. In addition, mono-olefination for aryl phosphonates is observed using a phosphonic diamide directing group. |
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| ISSN: | 1477-0520 1477-0539 |
| DOI: | 10.1039/c3ob41548a |