Mechanistic Insights and Kinetic Analysis for the Oxidative Hydroxylation of Arylboronic Acids by Visible Light Photoredox Catalysis: A Metal-Free Alternative
The photocatalytic hydroxylation of boronic acids with methylene blue as photosensitizer proceeds with high efficiency. Detailed time-resolved studies of the relevant rate constants provide a clear mechanistic understanding of excited-state processes and guided the selection of the photocatalyst and...
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| Veröffentlicht in: | Journal of the American Chemical Society 2013-09, Vol.135 (36), p.13286-13289 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The photocatalytic hydroxylation of boronic acids with methylene blue as photosensitizer proceeds with high efficiency. Detailed time-resolved studies of the relevant rate constants provide a clear mechanistic understanding of excited-state processes and guided the selection of the photocatalyst and the optimization of experimental conditions. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/ja406311g |