Efficient Diels–Alder Addition of Cyclopentadiene to Lithium Ion Encapsulated [60]Fullerene

Efficient Diels–Alder Addition of Cyclopentadiene to Lithium Ion Encapsulated [60]Fullerene

Much higher reactivity of [Li+@C60]PF6 – for Diels–Alder cycloaddition toward cyclopentadiene (CpH), in comparison with that of empty C60, was observed. The synthetic method, electrochemical and light absorption properties, and X-ray crystal structure of the product [Li+@C60(CpH)]PF6 – are discussed...

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Veröffentlicht in:Organic letters 2013-09, Vol.15 (17), p.4466-4469
Hauptverfasser: Kawakami, Hiroki, Okada, Hiroshi, Matsuo, Yutaka
Format: Artikel
Sprache:eng
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Zusammenfassung:Much higher reactivity of [Li+@C60]PF6 – for Diels–Alder cycloaddition toward cyclopentadiene (CpH), in comparison with that of empty C60, was observed. The synthetic method, electrochemical and light absorption properties, and X-ray crystal structure of the product [Li+@C60(CpH)]PF6 – are discussed.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol4020046