(N,N-diethyldithiocarbamato)[tris(3,5-dimethylpyrazol-1-yl)hydroborato]copper(II): a new copper(II) dithiocarbamate compound with the classic Tp(Me2) scorpionate

(N,N-diethyldithiocarbamato)[tris(3,5-dimethylpyrazol-1-yl)hydroborato]copper(II): a new copper(II) dithiocarbamate compound with the classic Tp(Me2) scorpionate

The title complex, [Cu(C5H10NS2)(C15H22BN6)] or (Tp(Me2))Cu(S2CNEt2), incorporating the classic Tp(Me2) scorpionate, is relevant to blue copper protein models and to Cu extraction from waste treatment and mine-tailing leachate. The IR and UV-Vis spectra are consistent with the crystal structure.

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2013-09, Vol.69 (Pt 9), p.977-980
Hauptverfasser: Cañada, Louise Marie C, Yap, Glenn P A, Lim, Patrick John Y
Format: Artikel
Sprache:eng
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Zusammenfassung:The title complex, [Cu(C5H10NS2)(C15H22BN6)] or (Tp(Me2))Cu(S2CNEt2), incorporating the classic Tp(Me2) scorpionate, is relevant to blue copper protein models and to Cu extraction from waste treatment and mine-tailing leachate. The IR and UV-Vis spectra are consistent with the crystal structure.
ISSN:1600-5759
DOI:10.1107/S0108270113020192