Multiple Alkylation of Thiophene Derivatives with Simple and Extended Diarylcarbenium Ion Pools

Multiple Alkylation of Thiophene Derivatives with Simple and Extended Diarylcarbenium Ion Pools

The reactions of thiophene derivatives, bithiophene, and terthiophene with an electrochemically generated diarylcarbenium ion pool afforded multiple alkylation products. Extended diarylcarbenium ion pools afforded dendritic molecules by the multiple alkylation of bithophene and terthiophene.

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Veröffentlicht in:Denki kagaku oyobi kōgyō butsuri kagaku 2013-05, Vol.81 (5), p.399-401
Hauptverfasser: Nokami, T, Watanabe, T, Terao, K, Soga, K, Ohata, K, Yoshida, J-I
Format: Artikel
Sprache:jpn
Schlagworte:
Alkylation
Derivatives
Electrochemistry
Pools
Thiophenes
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Zusammenfassung:The reactions of thiophene derivatives, bithiophene, and terthiophene with an electrochemically generated diarylcarbenium ion pool afforded multiple alkylation products. Extended diarylcarbenium ion pools afforded dendritic molecules by the multiple alkylation of bithophene and terthiophene.
ISSN:1344-3542