The first structural confirmation of a C102 fullerene as C102Cl20 containing a non-IPR carbon cage

The first structural confirmation of a C102 fullerene as C102Cl20 containing a non-IPR carbon cage

The chlorination of a pristine C102 fullerene separated by HPLC from fullerene soot afforded crystals of C102Cl20 with a non-IPR (IPR = isolated pentagon rule) cage containing two pairs of fused pentagons; structural reconstruction of a two-step Stone-Wales rearrangement revealed the starting IPR is...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-09, Vol.49 (72), p.7944-7946
Hauptverfasser: Yang, Shangfeng, Wei, Tao, Wang, Song, Ignat'eva, Daria V, Kemnitz, Erhard, Troyanov, Sergey I
Format: Artikel
Sprache:eng
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Zusammenfassung:The chlorination of a pristine C102 fullerene separated by HPLC from fullerene soot afforded crystals of C102Cl20 with a non-IPR (IPR = isolated pentagon rule) cage containing two pairs of fused pentagons; structural reconstruction of a two-step Stone-Wales rearrangement revealed the starting IPR isomer (no. 19) of C102.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc44386h