A novel stereocontrolled approach to steroid side chain construction: asymmetric synthesis of potential synthon of the vitamin D series
Stereocontrolled synthesis of (−)-de-AB-8-oxa-cholest-14-en-9-one (2) as an optically active form was achieved starting from the methylene ketone (7). This work constitutes a formal synthesis of de-AB-cholestan (1).
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| Veröffentlicht in: | Tetrahedron letters 1984, Vol.25 (41), p.4669-4672 |
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| container_end_page | 4672 |
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| container_issue | 41 |
| container_start_page | 4669 |
| container_title | Tetrahedron letters |
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| creator | Nemoto, Hideo Kurobe, Hiroshi Fukumoto, Keiichiro Kametani, Tetsuji |
| description | Stereocontrolled synthesis of (−)-de-AB-8-oxa-cholest-14-en-9-one (2) as an optically active form was achieved starting from the methylene ketone (7). This work constitutes a formal synthesis of de-AB-cholestan (1). |
| doi_str_mv | 10.1016/S0040-4039(01)91229-8 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0040-4039 |
| ispartof | Tetrahedron letters, 1984, Vol.25 (41), p.4669-4672 |
| issn | 0040-4039 1873-3581 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_14191841 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Organic chemistry Preparations and properties Steroids |
| title | A novel stereocontrolled approach to steroid side chain construction: asymmetric synthesis of potential synthon of the vitamin D series |
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