A benign synthesis of 2-amino-4H-chromene in aqueous medium using hydrotalcite (HT) as a heterogeneous base catalyst

A simple and environmentally benign synthesis of 2-amino-4H-chromene is described using hydrotalcite as a solid base catalyst in aqueous medium. The catalysts were prepared by a co-precipitation method and well characterized by various techniques such as XRD, FT-IR, SEM and the basicity was found us...

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Veröffentlicht in:Catalysis science & technology 2013-01, Vol.3 (8), p.2050-2056
Hauptverfasser: Kale, Sandip R., Kahandal, Sandeep S., Burange, Anand S., Gawande, Manoj B., Jayaram, Radha V.
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Sprache:eng
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Zusammenfassung:A simple and environmentally benign synthesis of 2-amino-4H-chromene is described using hydrotalcite as a solid base catalyst in aqueous medium. The catalysts were prepared by a co-precipitation method and well characterized by various techniques such as XRD, FT-IR, SEM and the basicity was found using the phenol adsorption method. The reusability of the catalyst, use of water as a green solvent and easy isolation of the product along with good yields make the present protocol sustainable and advantageous compared to conventional methods.
ISSN:2044-4753
2044-4761
DOI:10.1039/c3cy20856g