Carbon balances in simulated atmospheric reactions: aromatic hydrocarbons
Inadequate measurements of carbon balances for aromatic hydrocarbon photoxidation systems, calculated as the sum of detected products, generally have been the case. Calculations of total gas-phase C during the reaction has yielded direct evidence for hetergeneous removal of intermediate products. Ex...
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| Veröffentlicht in: | Environ. Sci. Technol.; (United States) 1983-03, Vol.17 (3), p.183-186 |
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| container_end_page | 186 |
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| container_title | Environ. Sci. Technol.; (United States) |
| container_volume | 17 |
| creator | O'Brien, Robert J Green, Patrick J Nguyen Ngan Lien, . Doty, Richard A Dumdei, Bruce E |
| description | Inadequate measurements of carbon balances for aromatic hydrocarbon photoxidation systems, calculated as the sum of detected products, generally have been the case. Calculations of total gas-phase C during the reaction has yielded direct evidence for hetergeneous removal of intermediate products. Experiments with toluene reveal that 63% of C leaves the gas phase during the reaction. Normalized Co data in the test chambers, the saprc chamber, and the UNC chamber are compared to show their similarity. |
| doi_str_mv | 10.1021/es00109a013 |
| format | Article |
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Calculations of total gas-phase C during the reaction has yielded direct evidence for hetergeneous removal of intermediate products. Experiments with toluene reveal that 63% of C leaves the gas phase during the reaction. Normalized Co data in the test chambers, the saprc chamber, and the UNC chamber are compared to show their similarity.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es00109a013</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>400500 - Photochemistry ; 500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) ; AROMATICS ; ATMOSPHERIC CHEMISTRY ; CARBON ; CARBON COMPOUNDS ; CARBON DIOXIDE ; CARBON MONOXIDE ; CARBON OXIDES ; CHALCOGENIDES ; CHEMICAL REACTIONS ; CHEMISTRY ; ELEMENTS ; ENVIRONMENTAL SCIENCES ; HYDROCARBONS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MASS BALANCE ; MEASURING METHODS ; NONMETALS ; ORGANIC COMPOUNDS ; OXIDES ; OXYGEN COMPOUNDS ; PHASE STUDIES ; PHOTOCHEMICAL REACTIONS ; REACTION INTERMEDIATES ; SMOG ; TOLUENE</subject><ispartof>Environ. Sci. 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Calculations of total gas-phase C during the reaction has yielded direct evidence for hetergeneous removal of intermediate products. Experiments with toluene reveal that 63% of C leaves the gas phase during the reaction. Normalized Co data in the test chambers, the saprc chamber, and the UNC chamber are compared to show their similarity.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/es00109a013</doi><tpages>4</tpages></addata></record> |
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| identifier | ISSN: 0013-936X |
| ispartof | Environ. Sci. Technol.; (United States), 1983-03, Vol.17 (3), p.183-186 |
| issn | 0013-936X 1520-5851 |
| language | eng |
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| source | American Chemical Society Journals |
| subjects | 400500 - Photochemistry 500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) AROMATICS ATMOSPHERIC CHEMISTRY CARBON CARBON COMPOUNDS CARBON DIOXIDE CARBON MONOXIDE CARBON OXIDES CHALCOGENIDES CHEMICAL REACTIONS CHEMISTRY ELEMENTS ENVIRONMENTAL SCIENCES HYDROCARBONS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MASS BALANCE MEASURING METHODS NONMETALS ORGANIC COMPOUNDS OXIDES OXYGEN COMPOUNDS PHASE STUDIES PHOTOCHEMICAL REACTIONS REACTION INTERMEDIATES SMOG TOLUENE |
| title | Carbon balances in simulated atmospheric reactions: aromatic hydrocarbons |
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