Ionic conductivity of [Li+@C60](PF6(-)) in organic solvents and its electrochemical reduction to Li+@C60(·-)

Ionic conductivity of [Li+@C60](PF6(-)) in organic solvents and its electrochemical reduction to Li+@C60(·-)

The ionic conductivity of [Li(+)@C60](PF6(-)) was measured in o-dichlorobenzene, and found to be higher than that of TBA(+)PF6(-). Electrochemical reduction of [Li(+)@C60](PF6(-)) without any supporting electrolyte gave the monovalent radical anion Li(+)@C60˙(-), as confirmed by the characteristic E...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (67), p.7376-7378
Hauptverfasser: Ueno, Hiroshi, Kokubo, Ken, Nakamura, Yuji, Ohkubo, Kei, Ikuma, Naohiko, Moriyama, Hiroshi, Fukuzumi, Shunichi, Oshima, Takumi
Format: Artikel
Sprache:eng
Schlagworte:
Chlorobenzenes - chemistry
Electrochemical Techniques
Electrolytes - chemistry
Equipment Design
Fullerenes - chemistry
Ions - chemistry
Lithium - chemistry
Models, Molecular
Oxidation-Reduction
Phosphorus Compounds - chemistry
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Zusammenfassung:The ionic conductivity of [Li(+)@C60](PF6(-)) was measured in o-dichlorobenzene, and found to be higher than that of TBA(+)PF6(-). Electrochemical reduction of [Li(+)@C60](PF6(-)) without any supporting electrolyte gave the monovalent radical anion Li(+)@C60˙(-), as confirmed by the characteristic ESR signal and NIR absorption band.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc43901a