Domino Reaction Catalyzed by Zeolites with Brønsted and Lewis Acid Sites for the Production of γ-Valerolactone from Furfural

Take the straight path: Furfural was converted into γ‐valerolactone (GVL) through sequential transfer‐hydrogenation and hydrolysis reactions catalyzed by zeolites with Lewis and Brønsted acid sites (see picture). Together, Zr‐Beta and Al‐MFI nanosheets generated GVL in 78 % yield without the use of...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-07, Vol.52 (31), p.8022-8025
Hauptverfasser: Bui, Linh, Luo, Helen, Gunther, William R., Román-Leshkov, Yuriy
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Sprache:eng
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Zusammenfassung:Take the straight path: Furfural was converted into γ‐valerolactone (GVL) through sequential transfer‐hydrogenation and hydrolysis reactions catalyzed by zeolites with Lewis and Brønsted acid sites (see picture). Together, Zr‐Beta and Al‐MFI nanosheets generated GVL in 78 % yield without the use of precious metals or molecular H2. This system offers an attractive streamlined strategy for the production of GVL from biomass‐derived molecules.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201302575