Stabilisation of strawberry (Fragaria x ananassa Duch.) anthocyanins by different pectins
•Low potential of pectins for stabilisation of strawberry anthocyanins.•Best pigment stabilisation was provided by apple and sugar beet pectin.•Amount of co-pigments had minor effect on strawberry anthocyanin stability.•Stabilising effect of pectins on strawberry pigments was weaker compared to blac...
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Veröffentlicht in: | Food chemistry 2013-12, Vol.141 (3), p.2998-3006 |
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Sprache: | eng |
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Zusammenfassung: | •Low potential of pectins for stabilisation of strawberry anthocyanins.•Best pigment stabilisation was provided by apple and sugar beet pectin.•Amount of co-pigments had minor effect on strawberry anthocyanin stability.•Stabilising effect of pectins on strawberry pigments was weaker compared to black currant.•A mode of action for anthocyanin–pectin stabilisation is proposed.
The objective of the present study was to evaluate the effects of different pectins on strawberry anthocyanins in viscous model solutions at pH 3.0. For this purpose, low esterified amidated, low and high methyl esterified citrus and apple pectins, and a sugar beet pectin (SBP), respectively, were added to strawberry extracts. The latter were predominantly composed of pelargonidin-glycosides, containing either reduced (E-1) or original amounts of non-anthocyanin phenolics (E-2). Model systems were stored for 18weeks at 20±0.5°C protected from light, and anthocyanins were quantitated in regular intervals by HPLC-DAD analyses. Half-life (t1/2) and destruction (D) values were calculated based on first-order kinetics. Generally, significant differences in pigment retention could be ascribed to differing pectin sources, while variation in the degree of esterification and amidation, respectively, had negligible effects. Compared to systems without added pectin, apple pectins and SPB enhanced anthocyanin stability moderately, while stabilising effects of citrus pectins were poor or even imperceptible. Generally, the amount of non-anthocyanin phenolics and the addition of citrate did not markedly affect anthocyanin stability. However, pectins had no influence on total phenolic contents (Folin-Ciocalteu assay) and antioxidant capacities (FRAP and TEAC assay) of strawberry phenolics over time. For pelargonidin-3-glucoside and -rutinoside largely consistent stabilities were found in all model systems. In contrast, pelargonidin-3-malonylglucoside was less stable in the blank, and stabilisation by pectins was always negligible. The findings of the present study are contrary to results reported previously for the stabilisation of cyanidin- and delphinidin-glycosides in similar model systems prepared with black currant extracts, indicating a high impact of the number of hydroxyl groups in the anthocyanin B-ring. |
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ISSN: | 0308-8146 1873-7072 |
DOI: | 10.1016/j.foodchem.2013.04.117 |