Dual-Stimulus Luminescent Lanthanide Molecular Switch Based on an Unsymmetrical Diarylperfluorocyclopentene

A [2]pseudorotaxane formed from an unsymmetrical diarylperfluorocyclopentene (1) and a Eu3+ complex of terpyridinyldibenzo-24-crown-8 (2) revealed excellent reversible lanthanide luminescence switching behavior dual-modulated by host–guest and optical stimuli.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2013-07, Vol.135 (28), p.10190-10193
Hauptverfasser:	Cheng, Hong-Bo, Zhang, Heng-Yi, Liu, Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Cyclopentanes - chemistry Europium - chemistry Luminescence Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Rotaxanes - chemical synthesis Rotaxanes - chemistry
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Beschreibung
Zusammenfassung:	A [2]pseudorotaxane formed from an unsymmetrical diarylperfluorocyclopentene (1) and a Eu3+ complex of terpyridinyldibenzo-24-crown-8 (2) revealed excellent reversible lanthanide luminescence switching behavior dual-modulated by host–guest and optical stimuli.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja4018804