Enantioselective synthesis of (+)- and (−)-cis-2-methyl-4-propyl-1,3-oxathiane and their olfactive properties

Enantioselective synthesis of (+)- and (−)-cis-2-methyl-4-propyl-1,3-oxathiane and their olfactive properties

The enantioselective synthesis of (+)‐ and (−)‐cis‐2‐methyl‐4‐propyl‐1,3‐oxathine 8 and 9 form (E)‐2‐hezen‐1‐ol (1) as common starting material is described. The two enantiomeric forms exhibit different organoleptic properties.

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Veröffentlicht in:Helvetica chimica acta 1984-06, Vol.67 (4), p.947-952
Hauptverfasser: Pickenhagen, Wihelm, Brönner-Schindler, Helene
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Preparations and properties
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Zusammenfassung:The enantioselective synthesis of (+)‐ and (−)‐cis‐2‐methyl‐4‐propyl‐1,3‐oxathine 8 and 9 form (E)‐2‐hezen‐1‐ol (1) as common starting material is described. The two enantiomeric forms exhibit different organoleptic properties.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.19840670405