Superhydrophobic perfluorinated metal-organic frameworks

Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 ± 1°, they are among the most water-repellen...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-08, Vol.49 (61), p.6846-6848
Hauptverfasser:	Chen, Teng-Hao, Popov, Ilya, Zenasni, Oussama, Daugulis, Olafs, Miljanić, Ognjen Š
Format:	Artikel
Sprache:	eng
Schlagworte:	Copper - chemistry Hydrophobic and Hydrophilic Interactions Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 ± 1°, they are among the most water-repellent MOFs ever reported.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c3cc41564c